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Beilstein J. Org. Chem. 2015, 11, 1136–1147, doi:10.3762/bjoc.11.128
Graphical Abstract
Figure 1: Chemical structures of 1–9 and TTP.
Scheme 1: Synthesis of 5–9.
Figure 2: Molecular orbitals of 5a (trans isomer).
Figure 3: Molecular orbitals of 6a (trans isomer).
Figure 4: Molecular orbitals of 8a (trans isomer).
Figure 5: Deconvoluted cyclic voltammograms of (a) 5d, (b) 7d and (c) 9d.
Scheme 2: Plausible redox processes of 5d and 7d.
Scheme 3: Plausible redox process of 9d.
Figure 6: (a) Galvanostatic charge-discharge curves of (a) 5c/Li and (b) 6b/Li cells.
Figure 7: Cycle-life performances for 5b/Li, 5c/Li and 6b/Li cells.
Figure 8: (a) Galvanostatic charge–discharge curves, and (b) cycle-life performances for a 8c/Li cell.
Figure 9: Molecular structures of 20 and 21.